Moreover, after restarting the boiler, several load changes was recorded. Load change is one of the main causes of phosphate hideout in which phosphate precipitates and consequently free caustic may form [13,16]. Therefore, as a result of load changes and bulk
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22/3/2009 · Many U.S. electric utilities have converted their drum boilers to caustic treatment and eliminated problems such as phosphate hideout. This paper will discuss the basics of caustic treatment and present some case histories of successful operation in a caustic boiler water treatment regimen.
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Phosphate Hideout What is phosphate hideout? Phosphate hideout is a phenomenon that causes boiler water control difficulties. It is defined as the disappearance, by precipitation or absorption, of the ionic phosphate (PO4) species, in the boiler water under high heat transfer or high load conditions.
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The minimum phosphate is 0.2 mg/L. PC(L) or Phosphate Continuum (Low) requires higher purity feedwater, but uses lower phosphate target ranges and minimizes the propensity for phosphate hideout. PC(H) or Phosphate Continuum (High) is the most forgiving program if there are upsets in boiler feedwater quality, but it does increase the propensity for phosphate hideout.
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instance, phosphate treatments often result in hideout and hideout return in higher pressure boilers/evaporators (>10.4 MPa, 1500 psi), and some treatments can result in a UDC tube failure mechanism, acid phosphate corrosion [6]. Phosphate is also sometimes
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23/6/2006 · There are some EPRI papers on the subject. As I recall, there was a buzz of research on that topic about 20 yrs ago. If the unit is a high pressure boiler ( MCR drum pressure approx 2800 psig) much of the phosphate will precipitate out of solution onto the hot inside surface of boiler tubes if the tube wall temp is above ( 650 F ?).
Read MoreElevated temperatures at the boiler tube wall or deposits can result in some precipitation of phosphate. This effect, termed "phosphate hideout," usually occurs when loads increase. When the load is reduced, phosphate reappears. Clean boiler water surfaces
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internal surfaces of the boiler (which is called phosphate hideout) leaving behind a high pH caustic solution [3, 4]. Hideout can occur with tri-sodium phosphate or when Na/PO4 is more than 2.6 for boilers suffer from scale deposition, it also occurs when more
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Why is the trisodium phosphate added to boiler feed water? Because it reacts with dissolved scaling impurities such as Mg 2+ ans Ca 2+ to form non-scaling precipitates of calcium and magnesium phosphates. This is removed from the boiler feed water
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20/10/2014 · It is universally followed that the Boiler Drum Water pH will be always higher than Feed Water and it will be in the range of 10.5 to 11 for Drum Water, and 8.2 to 8.5 for Feed Water. The Boiler Manufacturer has prescribed the Water Quality as follows in the Instruction Manual. TDS of Feed Water is 2 ppm, and for and Drum Water is 100 ppm.
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20/10/2014 · It is universally followed that the Boiler Drum Water pH will be always higher than Feed Water and it will be in the range of 10.5 to 11 for Drum Water, and 8.2 to 8.5 for Feed Water. The Boiler Manufacturer has prescribed the Water Quality as follows in the Instruction Manual. TDS of Feed Water is 2 ppm, and for and Drum Water is 100 ppm.
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1/12/2020 · Highlights. Failure of water wall tubes in a drum boiler (capacity of 550 t/h) is studied. Failure was due to periodic shutdowns, scale growth and rising temperature. The field data analysis showed phosphate hideout mechanism. Cleaning of outer surfaces of tubes and burner nozzles are …
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26/3/2013 · 2001. A. Doug - Yes copper in boiler feedwater can cause problems. The boiler chemicals that are used are there to help form a magnetite coating on the boiler tubes and protect them from corrosion. Magnetite is black oxide and most black oxide chemistries have rectifiers in them to help control metals that otherwise would inhibit the black
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